Weather Institute.
Terra Cave, Caught GROUDON.
How to find Groudon on Emerald: Visit the second floor of the Weather Institute and talk to the scientist at the far left end. He will tell you about heavy sunlight around such and such a route. If you visit that route, you will see the heavy sunlight. Now you just need to find a cave on that route. Follow the path to the end and you'll find a Lv.70 Groudon waiting for you.
*I recommend you to buy a lot of ultra balls and timer balls, and save your game before facing Groudon.
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